R. Bottcher et al., INDICATIONS OF AN INTERMEDIATE PHASE IN SINGLE-CRYSTALS OF BETAINE PHOSPHATE PHOSPHITE SOLID-SOLUTIONS/, Ferroelectrics, 208(1-4), 1998, pp. 105-124
The solid solution of ferroelectric betaine phosphite and antiferroele
ctric betaine phosphate shows an interesting phase diagram with a tran
sition from a high temperature prototype phase to a common nonpolar an
tiferrodistortive phase followed towards lower temperatures by transit
ions into ferroelectric, antiferroelectric or orientaional glass phase
s in dependence on its composition. Using magnetic resonance technique
s such as electron nuclear double resonance (ENDOR) and electron spin-
lattice relaxation measurements we are able to show that an intermedia
te phase exists between the antiferrodistortive and the orientational
glass phase at intermediate compositions. This new phase shows a regul
ar proton order within the phosphate-phosphite chains and is supposed
to be of quasiferroic or clusterlike nature.