Let M be a compact Riemannian manifold with smooth boundary partial de
rivative M. We study the asymptotic expansions associated with the gen
eralized heat operator Qe(-tPB) with suitable boundary conditions. A n
ew invariant defined on the boundary of M is introduced, and a method
is given that relates the heat content asymptotics for the generalized
heat operator and the standard heat operator e-(tPB) with the new bou
ndary asymptotics. As an application, we compute the boundary asymptot
ics associated with an operator of Laplace type, and the asymptotics f
or a generalized operator constructed from an operator of Dirac type.