MONTE-CARLO SIMULATION OF CURVATURE-ELASTIC INTERFACES

Citation
P. Pieruschka et S. Marcelja, MONTE-CARLO SIMULATION OF CURVATURE-ELASTIC INTERFACES, Langmuir, 10(2), 1994, pp. 345-350
Citations number
22
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
07437463
Volume
10
Issue
2
Year of publication
1994
Pages
345 - 350
Database
ISI
SICI code
0743-7463(1994)10:2<345:MSOCI>2.0.ZU;2-S
Abstract
We introduce a new Monte Carlo simulation technique for the equilibrat ion of curvature-elastic interfacial systems such as surfactant films dissolved in bulk media. The method is based on a continuous represent ation of the interfaces and can accurately evaluate all relevant surfa ce averages of the curvature Hamiltonian. We apply the method to spong e-like surfactant systems with the standard Hamiltonian, where the onl y parameters are the bending and saddle-splay moduli, kappa and kappaB AR. Random bicontinuous surface states are found to be stable for low bending rigidity and small negative saddle-splay modulus, justifying t he use of Gaussian ensembles as approximations to real interfacial ens embles. Topological changes of the random sponge states as a function of the ratio kappaBAR/kappa are analyzed; the results over a wide rang e Of kappa suggest that only this universal ratio determines whether t he final states resemble disordered minimal surfaces, disordered lamel lar, or connected parabolic geometries.