R. Vila et Mj. Decastro, THERMALLY STIMULATED POLARIZATION AND DEPOLARIZATION PROCESSES IN AL2O3-MG, Physical review. B, Condensed matter, 49(3), 1994, pp. 1696-1704
Thermally stimulated polarization (TSP) and depolarization current mea
surements in as-cut as well as in oxidized magnesium-doped aluminum ox
ide show a huge peak at around 265 K, another one at 245 K, and a broa
dband at higher temperatures. They are related to the presence of Mg-A
l(x), centers (substitutional magnesium ions with a hole trapped at a
neighboring oxygen ion) and originate from the thermally activated ion
ization of these centers, which release holes. The current-voltage cur
ves and the TSP results related to the main polarization process show
that this is due to the formation of blocking contacts at the sample-e
lectrode interfaces.