The electron yield from SiO2 films on Si was measured as a function of
oxide thickness and ion energy for 150-300 keV H+, He+, N+, Ne+, Ar+,
Kr+, and Xe+ ions. For oxide films thicker than 200 Angstrom, the ele
ctron yield was found to be approximately independent of oxide thickne
ss. The electron yield from the thick oxide increased as a function of
the energy deposited D in electronic excitations with approximately t
he form D-0.65 and not D as expected from theory. Close to the SiO2/Si
interface, unexpected variations in the electron yield with oxide thi
ckness, dependent on ion mass and energy, were found. Experiments were
performed to investigate whether or not the oxide surface was charged
by the ion beam, but such effects could not be observed. However, a s
atisfactory interpretation of the data could be obtained with a model
previously suggested for explaining the dependence of the electron yie
ld on the angle of ion incidence. In this model, the positive charge l
eft behind in the oxide by the liberated electrons within the electron
cascades of individual ions, causes the probability of escape of elec
trons to decrease with increasing electron yield.