C. Paschke et al., LOCAL MOMENTS AT THE METAL-INSULATOR-TRANSITION IN GE-SB AS PROBED WITH SPECIFIC-HEAT MEASUREMENTS IN MAGNETIC-FIELDS, Physical review. B, Condensed matter, 49(3), 1994, pp. 2170-2173
Specific-heat measurements at low temperatures (0.07 less than or equa
l to T less than or equal to 1.6 K) are reported for Ge:Sb with donor
concentrations between 0.6 and 4.0 x 10(17) cm(-3) spanning across the
metal-insulator transition at N-c = 1.44 x 10(17) cm(-3). The electro
nic coefficient gamma of the specific heat C is roughly twice as large
as expected for donor electrons with the Ge conduction-band effective
mass. Below about 0.3 K an additional contribution to C is found whic
h is attributed at least partly to exchange-coupled clusters of local
moments. This is supported by measurements of C in magnetic fields whe
re this contribution turns into a Schottky-like anomaly. Local moments
persist also in the metallic region of Ge:Sb as previously inferred f
rom magnetic susceptibility measurements. The dependence of the densit
y of local moments on donor concentration is similar to that found pre
viously in Si:P.