DETECTION OF UNPREDICTABLE MOLECULAR RECOGNITION THROUGH CARBONYL-PI INTERACTION IN POLY(METHYL ACRYLATE)-SILICA HYBRIDS

Authors
IHARA H UEMURA S OKAZAKI S HIRAYAMA C
Citation
H. Ihara et al., DETECTION OF UNPREDICTABLE MOLECULAR RECOGNITION THROUGH CARBONYL-PI INTERACTION IN POLY(METHYL ACRYLATE)-SILICA HYBRIDS, Polymer Journal, 30(5), 1998, pp. 394-397
Citations number
18
Categorie Soggetti
Polymer Sciences
Journal title
Polymer Journal → ACNP
ISSN journal
00323896
Volume
30
Issue
5
Year of publication
1998
Pages
394 - 397
Database
ISI
SICI code
0032-3896(1998)30:5<394:DOUMRT>2.0.ZU;2-9
Abstract
It was detected through grafting onto silica that atactic poly(methyl acrylate) showed unpredictably specific retention selectivity against polycyclic compounds with pi-electrons as if molecular-shape recogniti on was performed. This specificity was discussed with retention behavi ors in several other polymer-grafted silicas and by proposing a parame ter f to evaluate the contribution of pi-pi interaction.