KINETIC RESOLUTION OF RACEMIC ALLENES BY USING CHIRAL (SALEN)MANGANESE(III) COMPLEX AS A CATALYST

Authors
NOGUCHI Y TAKIYAMA H KATSUKI T
Citation
Y. Noguchi et al., KINETIC RESOLUTION OF RACEMIC ALLENES BY USING CHIRAL (SALEN)MANGANESE(III) COMPLEX AS A CATALYST, Synlett, (5), 1998, pp. 543
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
5
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):5<543:KRORAB>2.0.ZU;2-S
Abstract
Enantiomer-differentiating oxidation of racemic 1,3-diarylallenes usin g optically active (salen)manganese(III) complex (1) as a catalyst, wa s found to proceed with high relative rate constants (up to 23), provi ding the enantiomerically enriched 1,3-diarylallenes.