X-ray diffractometry and low-temperature exciton spectroscopy are used
to study heteroepitaxial CdSe/CdS layers grown at temperatures of 350
-485 degrees C by MOCVD, The high-temperature samples are found to dis
play the exciton and x-ray diffraction spectra characteristic of hexag
onal Wurtzite (W) structures, while the low-temperature samples displa
y the features characteristic of the cubic structure of sphalerite (ZB
). A number of the samples have x-ray spectra characteristic of struct
ures with stacking faults (SF), which represent a separate crystalline
phase in the structures studied here. It is found that the individual
crystalline phases are spatially separated. (C) 1998 American Institu
te of Physics.