A theoretical description of multiphonon decay processes of highly exc
ited localized modes is presented. Slowing of the decay rate at large
vibration amplitudes and jumps in the relaxation rate at certain criti
cal amplitudes are predicted. Highly excited vibrational states can ap
pear in localized excitons in crystals of noble gases and can also app
ear in hot luminescence. The observed and calculated spectra of Xe-2
in a Xe crystal are compared. (C) 1998 American Institute of Physics.