To successfully predict the performance of building materials exposed
to a degradative environment, transport properties must be either meas
ured or estimated. The development of relationships between microstruc
ture and transport properties for these materials should allow accurat
e prediction of the latter and an increased understanding of how micro
structure influences transport. Here, two microstructural characteriza
tion techniques, mercury intrusion porosimetry and scanning electron m
icroscopy, are combined with computer modelling techniques to compute
the vapor diffusivity and air permeability of three building materials
commonly exposed in building facades, two types of brick and a natura
l sandstone. In general, the computed values compare favorably to thos
e measured experimentally, thus demonstrating the capability of employ
ing microstructural characterization to predict transport properties.