SYNTHESES AND PROPERTIES OF OPTICALLY-ACTIVE NITRONYL NITROXIDE RADICALS

Two chiral nitronyl nitroxide substituted triazole derivatives have be en synthesized and characterized. Through the introduction of an optic ally pure substituent on the triazole moiety a discrimination over the possible conformers of the molecules is observed in the solid state. Syntheses, optical and magnet ic properties of the compounds as well a s the crystal structure of one of them are reported.