N-(9-ANTHRYL) AZA-18-CROWN-6 - PALLADIUM-CATALYZED SYNTHESIS, PHOTOPHYSICAL PROPERTIES AND CATION-BINDING ABILITY

Authors
WITULSKI B ZIMMERMANN Y DARCOS V DESVERGNE JP BASSANI DM BOUASLAURENT H
Citation
B. Witulski et al., N-(9-ANTHRYL) AZA-18-CROWN-6 - PALLADIUM-CATALYZED SYNTHESIS, PHOTOPHYSICAL PROPERTIES AND CATION-BINDING ABILITY, Tetrahedron letters, 39(27), 1998, pp. 4807-4808
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
27
Year of publication
1998
Pages
4807 - 4808
Database
ISI
SICI code
0040-4039(1998)39:27<4807:NA-PSP>2.0.ZU;2-3
Abstract
N-(9-Anthryl) aza-18-crown-6 (3) was synthesised via the palladium-cat alysed cross-coupling of 9-bromoanthracene (1) and aza-18-crown-6 (2). Its photophysical properties include an intramolecular charge-transfe r absorption band (lambda(max)approximate to 425 nm) in polar and nonp olar solvents, which disappears upon protonation or binding of K+ (log K-ass = 3.7 in acetonitrile). (C) 1998 Elsevier Science Ltd. All righ ts reserved.