IN SEARCH FOR THIOKETENE S-OXIDE - A VINYL SULFOXIDE TO SULFINE REARRANGEMENT

Authors
PELLOUXLEON N MINASSIAN F LEVILLAIN J RIPOLL JL VALLEE Y
Citation
N. Pellouxleon et al., IN SEARCH FOR THIOKETENE S-OXIDE - A VINYL SULFOXIDE TO SULFINE REARRANGEMENT, Tetrahedron letters, 39(27), 1998, pp. 4813-4816
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
27
Year of publication
1998
Pages
4813 - 4816
Database
ISI
SICI code
0040-4039(1998)39:27<4813:ISFTS->2.0.ZU;2-5
Abstract
Two approaches to thioketene S-oxide have been tested. This reactive h eterocumulene was tentatively characterized by low temperature IR spec troscopy. In the course of this study, an unexpected vinyl sulfoxide t o sulfine rearrangement was observed. (C) 1998 Elsevier Science Ltd. A ll rights reserved.