FIRST EXAMPLE OF DOUBLE-BOND MIGRATION IN THE ELECTROCHEMICAL CO2 INCORPORATION INTO (PERFLUOROALKYL)ALKENES

Authors
CHIOZZA E DESIGAUD M GREINER J DUNACH E
Citation
E. Chiozza et al., FIRST EXAMPLE OF DOUBLE-BOND MIGRATION IN THE ELECTROCHEMICAL CO2 INCORPORATION INTO (PERFLUOROALKYL)ALKENES, Tetrahedron letters, 39(27), 1998, pp. 4831-4834
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
27
Year of publication
1998
Pages
4831 - 4834
Database
ISI
SICI code
0040-4039(1998)39:27<4831:FEODMI>2.0.ZU;2-Y
Abstract
The electrochemical, nickel-catalyzed addition of CO2 to (perfluoroalk yl)alkenes leads to gamma-fluoro-gamma-(perfluoroalkyl)-beta-alkenyl c arboxylic acids, involving a double bond migration with loss of one fl uorine atom. (C) 1998 Elsevier Science Ltd. All rights reserved.