The ratio of marine to fluvial suspended matter in the Scheldt Estuary
was calculated by applying factor analysis to a data set of elemental
concentrations. The data set consisted of 98 samples collected under
various river discharge conditions. Each sample was analysed for the c
oncentration of Cr, Pb, Fe, Mn, Ni, Co, Ba, Zn, Cu, Cd, S, Ca, Sr, Ag,
Sn and Na. Five linearly independent processes were found to describe
the variability of the elemental concentrations: (1) the supply of fl
uvial material to the mixing zone; (2) manganese oxidation in the tran
sition area between the anoxic upper estuary and the oxic lower estuar
y; (3) the supply of marine material to the mixing zone; (4) a phytopl
ankton bloom in the lower estuary; and (5) the formation of insoluble
metal sulphides in the anoxic high-turbidity zone. Scores of the first
and third factor were used to calculate the ratio of marine to fluvia
l suspended matter in the mixing zone. Information on the origin of bo
th the inorganic and organic fraction of suspended matter was obtained
in this way. (C) 1998 Academic Press Limited.