1-BENZYL-4-AZA-1-AZONIABICYCLO[2.2.2]OCTANE PERIODATE - A MILD AND EFFICIENT OXIDANT FOR THE CLEAVAGE OF OXIME DOUBLE-BONDS UNDER ANHYDROUSCONDITIONS

Authors
HAJIPOUR AR MAHBOUBGHAH N
Citation
Ar. Hajipour et N. Mahboubghah, 1-BENZYL-4-AZA-1-AZONIABICYCLO[2.2.2]OCTANE PERIODATE - A MILD AND EFFICIENT OXIDANT FOR THE CLEAVAGE OF OXIME DOUBLE-BONDS UNDER ANHYDROUSCONDITIONS, Journal of chemical research. Synopses, (3), 1998, pp. 122-123
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
3
Year of publication
1998
Pages
122 - 123
Database
ISI
SICI code
0308-2342(1998):3<122:1P-AMA>2.0.ZU;2-1
Abstract
1-Benzyl-4-aza-1-azoniabicyclo [2.2.2]octane periodate (BAABCP) (1), r eadily prepared from commercially available 1,4-diazabicyclo[2.2.2] oc tane (DABCO) and sodium periodate, converts oximes and alpha-sulfinyl oximes to the corresponding carbonyl compounds and beta-keto sulfoxide s, respectively, in high yields and high enantiomeric purity.