ELECTROGENERATED SUPEROXIDE INDUCED OXIDATION OF THIOLS AND DISULFIDEINTERCHANGE - A FUNCTIONAL-GROUP APPROACH TO BIOMIMETIC STUDY

Citation
S. Singh et al., ELECTROGENERATED SUPEROXIDE INDUCED OXIDATION OF THIOLS AND DISULFIDEINTERCHANGE - A FUNCTIONAL-GROUP APPROACH TO BIOMIMETIC STUDY, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 37(4), 1998, pp. 411-414
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03764699
Volume
37
Issue
4
Year of publication
1998
Pages
411 - 414
Database
ISI
SICI code
0376-4699(1998)37:4<411:ESIOOT>2.0.ZU;2-X
Abstract
Thiols are readily oxidized to disulfides using electro-lytically gene rated superoxide ion in dimethylformamide. Unsymmetrical disulfides ar e obtained as a result of interchange between two different symmetrica l disulfides under the same set of reaction conditions.