Tribological behaviors of amorphous diamond-like carbon (DLC) films we
re experimentally evaluated under various environments using a steel b
all-on-disk wear-rig at dry sliding surfaces. The DLC films were prepa
red on Si wafer by r.f. PACVD method using benzene (C,H,). Every test
was performed under the normal load 4.9 N and sliding velocity of 0.05
m/s, and the coefficients of friction of DLC films were measured with
the contact cycle. When the test was performed under a vacuum, the co
efficient of friction of DLC films showed a significant fluctuation wi
th the contact cycles, remarkably accompanied with roll-shaped polymer
ic wear debris. Another test using thermally-baked DLC films showed th
at the friction was lower and more stable. Under a humidity controlled
air, friction of DLC films was also stable. Tests with dry 0, and N,
gas were extended to find any other environmental factors which could
affect the tribological behavior of DLC films. It was found that tribo
logical behavior of DLC films was dependent on the formation of fricti
on layers which were mainly affected by the environment. In the final
discussion of this work effects of environment on the tribological beh
avior of DLC films were combined and discussed in terms of tribe-chemi
stry of DLC films. (C) 1998 Elsevier Science S.A. All rights reserved.