THERMODYNAMICAL INVESTIGATIONS OF SOME NONELECTROLYTIC TERNARY MIXTURES

Citation
Kc. Kalra et al., THERMODYNAMICAL INVESTIGATIONS OF SOME NONELECTROLYTIC TERNARY MIXTURES, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 37(4), 1998, pp. 308-315
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710 → ACNP
Volume
37
Issue
4
Year of publication
1998
Pages
308 - 315
Database
ISI
SICI code
0376-4710(1998)37:4<308:TIOSNT>2.0.ZU;2-N
Abstract
Molar excess volume, V-ijk(E) and molar excess enthalpies H-ijk(E) of various nitrobenzene (i) + benzene (j) + toluene (k) nitrobenzene (i) + benzene (i) + o- xylene (k) and nitrobenzene (i) + benzene (j) + p-x ylene (k) ternary mixtures have been measured as a function of composi tion at 298.15 K. The observed data have been analysed in terms of i) Graph theory, ii) Sanchez and Lacombe and iii) Flory's theories. The c alculated X-ijk(E) values(X = V or H) by Graph and Flory's theories co mpare well with their corresponding experimental values.