REACTIONS OF [M-2(CO)(10)] (M = MN OR RE) WITH XENON BIS[PENTAFLUOROOXO-TELLURATE(VI) AND BIS[PENTAFLUOROOXO-SELENATE(VI)]

Authors
CROSSMAN MC HOPE EG WOOTTON LJ
Citation
Mc. Crossman et al., REACTIONS OF [M-2(CO)(10)] (M = MN OR RE) WITH XENON BIS[PENTAFLUOROOXO-TELLURATE(VI) AND BIS[PENTAFLUOROOXO-SELENATE(VI)], Journal of the Chemical Society. Dalton transactions, (11), 1998, pp. 1813-1817
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
11
Year of publication
1998
Pages
1813 - 1817
Database
ISI
SICI code
0300-9246(1998):11<1813:RO[(=M>2.0.ZU;2-M
Abstract
The oxidation of [M-2(CO)(10)] (M = Mn or Re) with Xe(OEF5)(2) (E = Se or Te) in dichloromethane at room temperature afforded [M(OEF5)(CO)(5 )] (M = Mn or Re, E = Se or Te) which have been characterised by mass spectrometry, IR and NMR spectroscopies and extended X-ray absorption fine structure (EXAFS) spectroscopy.