REDOX BEHAVIOR OF AZULENYL NITRONES - FULLY REVERSIBLE ONE-ELECTRON OXIDATION BY CYCLIC VOLTAMMETRY AT POTENTIALS IN THE RANGE OF BIOLOGICAL ANTIOXIDANTS
Da. Becker et al., REDOX BEHAVIOR OF AZULENYL NITRONES - FULLY REVERSIBLE ONE-ELECTRON OXIDATION BY CYCLIC VOLTAMMETRY AT POTENTIALS IN THE RANGE OF BIOLOGICAL ANTIOXIDANTS, Perkin transactions. 2, (6), 1998, pp. 1289-1291
The one electron oxidation chemistry of azulenyl nitrones 4 and 5 empl
oying cyclic voltammetry reveals that, unlike conventional nitrone spi
n traps such as PEN and S-PBN, such oxidation is electrochemically and
chemically reversible at potentials near or within those of Important
biological chain-breaking antioxidants.