COUPLING-CONSTANTS (1)J(N-15,P-31) AS A PROBE FOR THE CONFORMATIONAL EQUILIBRIA OF 2-AMINO-SUBSTITUTED 1,3,2-LAMBDA(5)-OXAZAPHOSPHINAN-2-ONES

Authors
VILJANEN T KLIKA KD FULOP F PIHLAJA K
Citation
T. Viljanen et al., COUPLING-CONSTANTS (1)J(N-15,P-31) AS A PROBE FOR THE CONFORMATIONAL EQUILIBRIA OF 2-AMINO-SUBSTITUTED 1,3,2-LAMBDA(5)-OXAZAPHOSPHINAN-2-ONES, Perkin transactions. 2, (6), 1998, pp. 1479-1481
Citations number
19
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
6
Year of publication
1998
Pages
1479 - 1481
Database
ISI
SICI code
0300-9580(1998):6<1479:C(AAPF>2.0.ZU;2-T
Abstract
The N-15 NMR spectra of both P(2) diastereomers of the trans-fused hlo roethyl)amino-3,4,4a,5,6,7,8,8a-octahydro-1,3,2 lambda(5)-benzoxazapho sphinin-2-ones and their 3-methyl and 3-benzyl derivatives have been m easured. Depending on the P(2) configuration, the coupling constants ( 1)J(N-15,P-31) vary markedly. The applicability of the coupling betwee n exocyclic nitrogen and phosphorus for determination of the heterorin g conformation is discussed.