We have studied trapping kinetics of defects during carrier capture in
heavily damaged silicon, where damage was induced by MeV heavy ions a
t doses near but below the amorphization threshold. Using spectroscopi
c junction transient measurements, we provide unambiguous evidence of
charge redistribution between defects. These results imply that change
s in the occupancy of gap states are responsible for the deepening of
emission energies with filling time, as is commonly observed in transi
ent experiments in disordered silicon. This is in contrast to its usua
l explanation in terms of deepening of energy states due to hierarchic
al defect relaxation.