SIGMA-DELOCALIZED HEXAKIS(METHYLTHIO)BENZENE DICATION - A POSSIBLE INTERMEDIATE OF PUMMERER-TYPE REARRANGEMENT OF MONOOXIDE OF HEXAKIS(METHYLTHIO) BENZENE

Authors
KOBAYASHI K TAKAHASHI O NAMATAME K KIKUCHI O FURUKAWA N
Citation
K. Kobayashi et al., SIGMA-DELOCALIZED HEXAKIS(METHYLTHIO)BENZENE DICATION - A POSSIBLE INTERMEDIATE OF PUMMERER-TYPE REARRANGEMENT OF MONOOXIDE OF HEXAKIS(METHYLTHIO) BENZENE, Chemistry Letters, (6), 1998, pp. 515-516
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1998
Pages
515 - 516
Database
ISI
SICI code
0366-7022(1998):6<515:SHD-AP>2.0.ZU;2-8
Abstract
The Pummerer-type rearrangement of monooxide of hexakis(methylthio)ben zene with H2SO4 or (CF3SO2)(2)O gives the cyclic methylsulfonium salt. A sigma-delocalized hexathia dication is proposed as an intermediate.