S. Onaka et al., CONSTRUCTION OF A CRYSTALLINE TETRAMER AND INFINITE NETWORK THROUGH THE DUAL-USE OF AU(I)-AU(I) AND PI-PI INTERACTIONS, Chemistry Letters, (6), 1998, pp. 525-526
SC6H5 was substituted for Cl in AuCl(PPh3) and (AuCl)(2)(trans-Ph2PCH=
CHPPh2) by reacting with Sn(SC6H5)(n- Bu)(3) in refluxing THF. Both pr
oducts exhibit new three-dimensional motifs which are created by Au ..
. Au interaction and pi-pi interaction between phenyl rings in crystal
s.