CONSTRUCTION OF A CRYSTALLINE TETRAMER AND INFINITE NETWORK THROUGH THE DUAL-USE OF AU(I)-AU(I) AND PI-PI INTERACTIONS

Authors
ONAKA S KATSUKAWA Y YAMASHITA M
Citation
S. Onaka et al., CONSTRUCTION OF A CRYSTALLINE TETRAMER AND INFINITE NETWORK THROUGH THE DUAL-USE OF AU(I)-AU(I) AND PI-PI INTERACTIONS, Chemistry Letters, (6), 1998, pp. 525-526
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1998
Pages
525 - 526
Database
ISI
SICI code
0366-7022(1998):6<525:COACTA>2.0.ZU;2-R
Abstract
SC6H5 was substituted for Cl in AuCl(PPh3) and (AuCl)(2)(trans-Ph2PCH= CHPPh2) by reacting with Sn(SC6H5)(n- Bu)(3) in refluxing THF. Both pr oducts exhibit new three-dimensional motifs which are created by Au .. . Au interaction and pi-pi interaction between phenyl rings in crystal s.