PHOTON-INDUCED, REDUCTANT-INDUCED, AND OXIDANT-INDUCED SUBSTITUTION OF A CO-LIGAND ON CLOSO-[CP-ASTERISK-2FE3S2(CO)(3)] (CP-ASTERISK = ETA(5)-C5ME5)

Authors
YUKI M MITSUI T INOMATA S OKAZAKI M OGINO H
Citation
M. Yuki et al., PHOTON-INDUCED, REDUCTANT-INDUCED, AND OXIDANT-INDUCED SUBSTITUTION OF A CO-LIGAND ON CLOSO-[CP-ASTERISK-2FE3S2(CO)(3)] (CP-ASTERISK = ETA(5)-C5ME5), Chemistry Letters, (6), 1998, pp. 561-562
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1998
Pages
561 - 562
Database
ISI
SICI code
0366-7022(1998):6<561:PRAOSO>2.0.ZU;2-V
Abstract
Substitution of CO in closo-[Cp2Fe3S2(CO)(3)] (1) by PPh3 was acceler ated upon photolysis or by treatment with reductant or oxidant to give mono(PPh3)-substituted clusters. In the redox-induced reaction, [1](- ) and [1](+) were proposed as labile intermediates to substitution of CO.