EFFECTIVE RUTHENIUM-CATALYZED OXIDATION OF CHLORINATED OLEFINS BY MONOPERSULFATE IN AQUEOUS-MEDIUM

Authors
BRESSAN M FORTI L MORVILLO A
Citation
M. Bressan et al., EFFECTIVE RUTHENIUM-CATALYZED OXIDATION OF CHLORINATED OLEFINS BY MONOPERSULFATE IN AQUEOUS-MEDIUM, Journal of the Chemical Society, Chemical Communications, (3), 1994, pp. 253-254
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
3
Year of publication
1994
Pages
253 - 254
Database
ISI
SICI code
0022-4936(1994):3<253:EROOCO>2.0.ZU;2-7
Abstract
In aqueous medium, in the presence of a surfactant agent and of cataly tic amounts of ruthenium derivatives, monopersulfate effectively oxidi zes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 tu rnover min(-1) at room temperature.