A NOVEL SYNTHESIS OF CYCLIC NITRONES VIA A NITROSOKETENE INTERMEDIATE
Citation
N. Katagiri et al., A NOVEL SYNTHESIS OF CYCLIC NITRONES VIA A NITROSOKETENE INTERMEDIATE, Journal of the Chemical Society, Chemical Communications, (3), 1994, pp. 281-282
Categorie Soggetti
Chemistry
SICI code
0022-4936(1994):3<281:ANSOCN>2.0.ZU;2-F
Abstract
Nitrosoketene generated by thermolysis of hydroxyimino Meldrum's acid
1 reacts with various ketones including the chiral ketone (+)-nopinone
to produce cyclic nitrones 2-5 as novel 1,3-dipolar molecules.