Residual stresses (RS) are induced in metallic materials by a variety
of working and fabrication processes. They are generally classified in
to three categories'(types I, II and III) depending upon their range o
f influence. Separation of type I and II stresses often requires stres
s measurements on thin specimens. Type III stresses are related closel
y to grain fragmentation and micro-strains associated with plastic def
ormation. Perhaps the oldest and the most rigorous method of estimatin
g these stresses is still the Warren-Averbach analysis developed durin
g the late forties/early fifties. Other techniques involving integral
breadths and variance of the profiles have also been developed. In all
these methods developed during the early stages, prior to seventies,
a major requirement was well-separated non-overlapping profiles. The l
ate sixties and early seventies saw a dramatic increase in computation
al capabilities with the advent of powerful electronic computers. This
led to the introduction of curve-fitting procedures into the field of
X-ray diffraction. The most remarkable achievement of this period is
the development of the Rietveld Method. Although this method was initi
ally developed to tackle the neutron diffraction profiles, which are a
s a rule nearly symmetric and Gaussian in nature, the method saw rapid
developments during the eighties. At present, techniques based on con
cepts developed by Rietveld could be applied to essentially asymmetric
and non-Gaussian multiple spectral components of X-ray diffraction pr
ofiles. Pattern decomposition techniques which separate composite-powd
er diffraction profiles into individual profiles are now available. In
combination with single line profile analysis techniques, this provid
es a powerful tool in the hands of researchers. A typical example of s
uch a single line profile analysis is given.