GaAs(100) surfaces with adsorbed Se or Te have been studied using scan
ning tunneling microscopy (STM), x-rav-photoemission spectroscopy (XPS
), and electron diffraction, STM reveals uniform dimerization which is
consistent with the 2 X 1 symmetry of the electron diffraction. XPS s
hows an initial single-monolayer coverage of Se followed by a slow Se
uptake which predominantly replaces As. Narrow single- and double-bila
yer high islands, which are long in the [011] direction of dimer rows,
are generally observed as well as terrace edges which show related ki
nk anisotropy. Possible surface structures are discussed.