RB4SN2AG4(P2SE6)(3) - FIRST EXAMPLE OF A QUINARY SELENOPHOSPHATE AND AN UNUSUAL SN-AG S(2)-D(10) INTERACTION

Authors
CHONDROUDIS K KANATZIDIS MG
Citation
K. Chondroudis et Mg. Kanatzidis, RB4SN2AG4(P2SE6)(3) - FIRST EXAMPLE OF A QUINARY SELENOPHOSPHATE AND AN UNUSUAL SN-AG S(2)-D(10) INTERACTION, Inorganic chemistry, 37(12), 1998, pp. 2848-2849
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
12
Year of publication
1998
Pages
2848 - 2849
Database
ISI
SICI code
0020-1669(1998)37:12<2848:R-FEOA>2.0.ZU;2-V
Abstract
The flux synthesis of the layered compound Rb4Sn2-Ag4P6Se18 is reporte d. Multiply bonded [P2Se6](4-) ligands hold together Sn2+ and Ag+ atom s, stabilizing a novel Sn-Ag s(2)-d(10) bonding interaction at 2.866-( 2) Angstrom.