SYNTHESIS OF 4 POSSIBLE INTERMEDIATES AFTER SECOLOGANIN ON THE BIOSYNTHESIS OF THE OLEOSIDE-TYPE, 10-HYDROXYOLEOSIDE-TYPE AND LIGUSTALOSIDE-TYPE GLUCOSIDES IN OLEACEOUS PLANTS
H. Kuwajima et al., SYNTHESIS OF 4 POSSIBLE INTERMEDIATES AFTER SECOLOGANIN ON THE BIOSYNTHESIS OF THE OLEOSIDE-TYPE, 10-HYDROXYOLEOSIDE-TYPE AND LIGUSTALOSIDE-TYPE GLUCOSIDES IN OLEACEOUS PLANTS, Chemical and Pharmaceutical Bulletin, 46(6), 1998, pp. 900-905
To examine the biosynthetic pathway from secologanin to three types of
secoiridoid glucosides characteristic of oleaceous plants, synthesis
of two respective stereoisomers at C-8 of 8,10-eposysecologanin and -s
ecoxyloganin was established and their deuterium-labeled analogues wer
e prepared.