CATALYTIC BEHAVIOR IN THE OLEFIN OXIDATION AND CHARACTERIZATION OF POLYACRYLONITRILE-PALLADIUM COMPLEXES

Authors
JIA CG JIN FY PAN HQ HUANG MY JIANG YY
Citation
Cg. Jia et al., CATALYTIC BEHAVIOR IN THE OLEFIN OXIDATION AND CHARACTERIZATION OF POLYACRYLONITRILE-PALLADIUM COMPLEXES, Macromolecular chemistry and physics, 195(2), 1994, pp. 751-758
Citations number
14
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
195
Issue
2
Year of publication
1994
Pages
751 - 758
Database
ISI
SICI code
1022-1352(1994)195:2<751:CBITOO>2.0.ZU;2-L
Abstract
We prepared polyacrylonitrile-palladium(PAN-Pd) complexes in which pal ladium is coordinated with approximately 2 nitrile groups and has a mi xed valency (Pd(0) + Pd(I) + Pd(II)). The complexes contain small pall adium aggregates (diameter ca. 50 angstrom) which are rather stable du e to the coordination of palladium to the polymer. The PAN-Pd complexe s are highly active and stable catalysts for the oxidation of olefins in the presence of cocatalysts like CuCl2.2H2O. They could be recycled 5 times without loss of activity in the oxidation of 1-heptene.