Collisions of ions, stored in a Penning trap, with neutral background
molecules usually lead to rapid ion loss from the trap unless the ions
are excited by tile sum of the frequencies of the reduced cyclotron a
nd magnetron motion. Then the ions are cooled by collisions and are dr
iven to the trap centre leading to substantial increase of the storage
time. Furthermore in a three level system including a long living met
astable state collisions deexcite this metastable state and increase t
he population density in the ionic ground state. In a laser spectrosco
pic experiment we demonstrate the advantages of collisions on Ba+ ions
stored in a Penning trap. The combined action of metastable state que
nching, axialisation and cooling leads to a significantly enhanced las
er induced fluorescence signal. The cross section for collisional rela
xation of the ground state Zeeman levels has been determined and we fi
nd that it is of the same order of magnitude as quenching cross sectio
n for a metastable state. Cooling and increased signal strength allows
us to observe extremely narrow resonances and motional sidebands in m
icrowave induced Zeeman transitions in the Ba+ electronic ground level
.