ELECTROPHILIC LIGAND ABSTRACTION FROM ELECTRON-RICH IRIDIUM(I) COMPLEXES WITH ME(3)-SIOTF - EVIDENCE FOR DIRECT LIGAND ATTACK

Authors
AIZENBERG M MILSTEIN D
Citation
M. Aizenberg et D. Milstein, ELECTROPHILIC LIGAND ABSTRACTION FROM ELECTRON-RICH IRIDIUM(I) COMPLEXES WITH ME(3)-SIOTF - EVIDENCE FOR DIRECT LIGAND ATTACK, Journal of the Chemical Society, Chemical Communications, (4), 1994, pp. 411-412
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1994
Pages
411 - 412
Database
ISI
SICI code
0022-4936(1994):4<411:ELAFEI>2.0.ZU;2-J
Abstract
Me3SiOTf(Tf=CF3SO2) is a useful reagent for electrophilic abstraction reactions involving electron-rich complexes RIrL(n) (R = H, Cl, Me, Ph ; L = PMe(3), PEt(3)); direct external attack of Me(3)Si(+) on R is pr obably involved.