ELECTROPHILIC AZIDO SELENENYLATION OF ALKENES - A SIMPLE SYNTHETIC ROUTE TO RACEMIC TAXOL SIDE-CHAIN

Authors
TIECCO M TESTAFERRI L TEMPERINI A BAGNOLI L MARINI F SANTI C
Citation
M. Tiecco et al., ELECTROPHILIC AZIDO SELENENYLATION OF ALKENES - A SIMPLE SYNTHETIC ROUTE TO RACEMIC TAXOL SIDE-CHAIN, Synthetic communications, 28(12), 1998, pp. 2167-2179
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
12
Year of publication
1998
Pages
2167 - 2179
Database
ISI
SICI code
0039-7911(1998)28:12<2167:EASOA->2.0.ZU;2-U
Abstract
Simple alkenes react with PhSeOTf and NaN3 in MeCN to afford beta-phen ylseleno azides as the result of a stereospecific trans addition. The regioselectivity of the process is determined by the structure of the alkene.