SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (I-MNT)(2)CENTER-DOT-0.5ME(2)CO-CENTER-DOT-0.5MECN - AN EXAMPLE OF UNSUPPORTED AU-1 ... AU-1 INTERACTIONS WITH [AU(PTA)(3)]-MNT=[S2C2(CN)(2)](2-))(, GIVING A NONLINEAR TETRANUCLEAR CHAIN (PTA=PHOSPHATRIAZAADAMANTANE, I)
Jp. Fackler et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (I-MNT)(2)CENTER-DOT-0.5ME(2)CO-CENTER-DOT-0.5MECN - AN EXAMPLE OF UNSUPPORTED AU-1 ... AU-1 INTERACTIONS WITH [AU(PTA)(3)]-MNT=[S2C2(CN)(2)](2-))(, GIVING A NONLINEAR TETRANUCLEAR CHAIN (PTA=PHOSPHATRIAZAADAMANTANE, I), Journal of the Chemical Society, Chemical Communications, (4), 1994, pp. 431-432
The water soluble complex [Au(pta)(3)]Cl reacts with K-2[i-mnt] to giv
e a non-linear, tetranuclear Au chain complex with an unprecedented st
ructure. e, i-mnt = [S2C2(CN)(2)](2-)}/