A FACILE BECKMANN REARRANGEMENT OF OXIMES WITH ALCL3 IN THE SOLID-STATE

Authors
GHIACI M IMANZADEH GH
Citation
M. Ghiaci et Gh. Imanzadeh, A FACILE BECKMANN REARRANGEMENT OF OXIMES WITH ALCL3 IN THE SOLID-STATE, Synthetic communications, 28(12), 1998, pp. 2275-2280
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
12
Year of publication
1998
Pages
2275 - 2280
Database
ISI
SICI code
0039-7911(1998)28:12<2275:AFBROO>2.0.ZU;2-A
Abstract
A facile and efficient synthetic procedure, for Beckmann rearrangement of oximes with AlCl3 in the absence of solvent is developed. We have been able to convert cyclohexanone oxime to epsilon-caprolactam in a q uantitative yield.