A NEW SYNTHESIS OF A FUNCTIONALIZED BICYCLO[5.4.0]UNDECANE SKELETON BASED ON A SEQUENCE INVOLVING [2-SCISSION OF ALKOXYL RADICALS GENERATEDFROM THE RESULTING CYCLOBUTANOLS(2] PHOTOADDITION AND REGIOSELECTIVE BETA)

Authors
SUGINOME H NAKAYAMA Y HARADA H HACHIRO H ORITO K
Citation
H. Suginome et al., A NEW SYNTHESIS OF A FUNCTIONALIZED BICYCLO[5.4.0]UNDECANE SKELETON BASED ON A SEQUENCE INVOLVING [2-SCISSION OF ALKOXYL RADICALS GENERATEDFROM THE RESULTING CYCLOBUTANOLS(2] PHOTOADDITION AND REGIOSELECTIVE BETA), Journal of the Chemical Society, Chemical Communications, (4), 1994, pp. 451-452
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1994
Pages
451 - 452
Database
ISI
SICI code
0022-4936(1994):4<451:ANSOAF>2.0.ZU;2-A
Abstract
A new general synthesis of a functionalized bicyclo[5.4.0]undecane ske leton based on a regioselective beta-scission of the alkoxyl radicals generated from 2-hydroxytricyclo[5.4.0.0(2,6)]undecan-8-ones (prepared by [2 + 2] photoaddition of cyclic enones with the trimethylsilyl eno l ethers of cyclic ketones) is described.