DIRECT SYNTHESES OF 1-PHENYLPHOSPHETANE AND 1-PHENYLPHOSPHIRANE - CRYSTAL AND MOLECULAR-STRUCTURES OF CYCLOTRIMERIZATION PRECURSOR COMPLEXES FAC-[MO(CO)(3)(PHPCH(2)CH(2)CH(2))(3)] AND FAC-[MO(CO)(3)(PHPCH(2)CH(2))(3)]

Authors
KANG YB PABEL M WILLIS AC WILD SB
Citation
Yb. Kang et al., DIRECT SYNTHESES OF 1-PHENYLPHOSPHETANE AND 1-PHENYLPHOSPHIRANE - CRYSTAL AND MOLECULAR-STRUCTURES OF CYCLOTRIMERIZATION PRECURSOR COMPLEXES FAC-[MO(CO)(3)(PHPCH(2)CH(2)CH(2))(3)] AND FAC-[MO(CO)(3)(PHPCH(2)CH(2))(3)], Journal of the Chemical Society, Chemical Communications, (4), 1994, pp. 475-476
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1994
Pages
475 - 476
Database
ISI
SICI code
0022-4936(1994):4<475:DSO1A1>2.0.ZU;2-N
Abstract
Dilithium phenylphosphide reacts with 1,3-dichloropropane or 1,2-dichl oroethane to give 1-phenylphosphetane or 1-phenylphosphirane, respecti vely; the free phosphines have been used to prepare the cyclotrimerisa tion precursor complexes fac[Mo(CO)(3)(PhPCH(2)CH(2)CH(2))(3)] and fac -[Mo(CO)(3)(PhPCH(2)CH(2))(3)].