DIASTEREOSELECTIVITY IN CHIRAL (ARENE)TRICARBONYLCHROMIUM HOMOBENZYLIC ALCOHOL COMPLEXES - ASYMMETRIC-SYNTHESIS OF DIHYDROISOCOUMARINS

Authors
THANGARASA R GREEN JR NADASDI TT
Citation
R. Thangarasa et al., DIASTEREOSELECTIVITY IN CHIRAL (ARENE)TRICARBONYLCHROMIUM HOMOBENZYLIC ALCOHOL COMPLEXES - ASYMMETRIC-SYNTHESIS OF DIHYDROISOCOUMARINS, Journal of the Chemical Society, Chemical Communications, (4), 1994, pp. 501-502
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1994
Pages
501 - 502
Database
ISI
SICI code
0022-4936(1994):4<501:DIC(H>2.0.ZU;2-7
Abstract
Enantiomerically pure (arene)tricarbonylchromium complexes of homobenz ylic ketones 3 undergo stereoselective reduction to give the correspon ding alcohols, which may be transformed readily into enantiomerically pure dihydroisocoumarins.