PULSED-LASER PHOTOLYSIS OF OS(PP(3))H-2 [PP(3)=P(CH2CH2PPH(2))(3)] - KINETIC SELECTIVITY FOR REACTION WITH METHANE

Authors
OSMAN R PATTISON DI PERUTZ RN BIANCHINI C PERUZZINI M
Citation
R. Osman et al., PULSED-LASER PHOTOLYSIS OF OS(PP(3))H-2 [PP(3)=P(CH2CH2PPH(2))(3)] - KINETIC SELECTIVITY FOR REACTION WITH METHANE, Journal of the Chemical Society, Chemical Communications, (4), 1994, pp. 513-514
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
4
Year of publication
1994
Pages
513 - 514
Database
ISI
SICI code
0022-4936(1994):4<513:PPOO[->2.0.ZU;2-N
Abstract
Transient absorption methods have been used to measure the reaction ki netics of Os(pp(3)) with hydrocarbons, following photodissociation of H-2 from Os(pp(3))H-2; the kinetic selectivity per reactive C-H bond f or pentane over cyclohexane exceeds 80 and that for methane over cyclo hexane exceeds 520, higher than any observed previously.