Sj. Angusdunne et al., A NOVEL HETEROPOLYMETALATE CONTAINING PALLADIUM(II) - SYNTHESIS AND CRYSTAL-STRUCTURE OF K2NA6[PD2W10O36]CENTER-DOT-22H(2)O, Journal of the Chemical Society, Chemical Communications, (4), 1994, pp. 523-524
The first well-characterised example of a heteropolymetalate involving
palladium, [Pd2W10O36](8-), contains two W5O186- 'ligands', each brid
ging between two four-coordinate palladium(II) ions in square-planar e
nvironments, defined by an X-ray crystal structure analysis.