ZN2-BASED ON ZN-BIS(2,4,4-TRIMETHYLPENTYL)DITHIOPHOSPHINIC ACID COMPLEX IN PVC MATRIX( SENSOR)

A zinc complex of the organic ion exchanger, bis(2,4,4-trimethylpentyl ) dithiophosphinic acid, has been used as an electroactive material fo r the preparation of PVC-based Zn2+-selective electrodes. The PVC matr ix incorporating sodium tetraphenylborate (NaTPB) as the anion exclude r and dibutyl(butyl)phosphonate (DBBP) as the solvent mediator along w ith the above complex in the ratio 7:29:5:59 (Zn-Cyanex-301:DBBP:NaTPB :PVC) exhibited a working concentration range of 2.8 x 10(-5)-1.0 x 10 (-1) M, with a slope of 30.1 mV per decade of activity and a fast resp onse time of 15 s. The valid pH range for the membrane sensor is 2.1-6 .9 and it can also be used in partially non-aqueous medium having upto 10% (v/v) non-aqueous content. The;sensor exhibits good selectivity o ver a number of other cations and has been applied as indicator electr ode in the potentiometric titration of Zn2+ against EDTA for the deter mination of end point. (C) 1998 Elsevier Science Ltd. All rights reser ved.