ELECTROCHEMICAL INVESTIGATIONS OF THE LIQUID LITHIUM (LICL-KCL EUTECTIC MELT) INTERFACE - CHRONOPOTENTIOMETRIC AND ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY MEASUREMENTS

Authors
HEBANT P PICARD GS
Citation
P. Hebant et Gs. Picard, ELECTROCHEMICAL INVESTIGATIONS OF THE LIQUID LITHIUM (LICL-KCL EUTECTIC MELT) INTERFACE - CHRONOPOTENTIOMETRIC AND ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY MEASUREMENTS, Electrochimica acta, 43(14-15), 1998, pp. 2071-2081
Citations number
32
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
43
Issue
14-15
Year of publication
1998
Pages
2071 - 2081
Database
ISI
SICI code
0013-4686(1998)43:14-15<2071:EIOTLL>2.0.ZU;2-8
Abstract
The liquid lithium/(LiCl-KCl eutectic melt) interface was studied usin g electroanalytical techniques (chronopotentiometry, cyclic voltammetr y and electrochemical impedance spectroscopy). The formation of a Li2C l layer has been shown and the role of residual oxide ions has been in vestigated. Results allow us to clarify the mechanism that leads to th e formation of a Li2Cl layer at the interface as well as its evolution with time. (C) 1998 Elsevier Science Ltd. All rights reserved.