FRACTAL APPROACH OF ACTIVATED CARBONS FROM SOLID-WASTE MATERIALS

Citation
K. Laszlo et al., FRACTAL APPROACH OF ACTIVATED CARBONS FROM SOLID-WASTE MATERIALS, Colloids and surfaces. A, Physicochemical and engineering aspects, 138(1), 1998, pp. 29-37
Citations number
33
Categorie Soggetti
Chemistry Physical
ISSN journal
09277757
Volume
138
Issue
1
Year of publication
1998
Pages
29 - 37
Database
ISI
SICI code
0927-7757(1998)138:1<29:FAOACF>2.0.ZU;2-T
Abstract
Carbonaceous composite materials were produced from various pyrolyzed organic waste materials by steam activation. Fractal dimensions derive d from SAXS and adsorption measurements were used to explain the chang es in the matrix and the surface microstructure, due to the activation . The comparison of the fractal dimensions from SAXS and nitrogen adso rption data can be successfully applied to understand the development of the porous structure. In these materials, of heterogeneous matrix, no correlation was found between the B.E.T. specific surface area and the fractal dimensions derived from various methods. The adsorption of different substrates is disturbed by the chemical heterogeneity of th e surface. In these cases, the applicability of aqueous solutions in t he description of the surface geometry might be questioned. (C) 1998 E lsevier Science B.V.