M. Trznadel, FRACTIONATED REGIOREGULAR POLY(3-HEXYLTHIOPHENE) - SPECTROSCOPIC AND ELECTROCHEMICAL STUDIES, Journal de chimie physique et de physico-chimie biologique, 95(6), 1998, pp. 1165-1167
Regioregular poly(3-hexylthiophene) was obtained and fractionated into
four fractions of different molecular weights (M-n) exhibiting low po
lydispersity coefficients. UV-VIS spectra confirm the increase of aver
age conjugation length with the increase of the M-n of fractions. Volt
ammetric curves of fractions corroborate UV-VIS results and show that
the contribution of poorly conjugated segments decrease with the M-n.