B. Beau et al., NMR-STUDY OF THE METALLIC STATE OF POLYAN ILINE-CSA, Journal de chimie physique et de physico-chimie biologique, 95(6), 1998, pp. 1437-1440
Proton nuclear relaxation times have been measured on PANI-CSA as a fu
nction of frequency and temperature. We found that PANI-CSA is not a c
lassical 3D metal. We have determined intra and interchain diffusion r
ates in the frame of a quasi-1D diffusion model, and their thermal dep
endence. Microscopic conductivity has been estimated. Results agree wi
th a quasi-1D metallic state.