ELECTROPOLYMERIZATION OF A CALIX[4]ARENE MODIFIED BY N-SUBSTITUTED PYRROLE MOIETIES - NEW SENSITIVE LAYER FOR IONIC ELECTROCHEMICAL DETECTION

Authors
BUFFENOIR A BIDAN G
Citation
A. Buffenoir et G. Bidan, ELECTROPOLYMERIZATION OF A CALIX[4]ARENE MODIFIED BY N-SUBSTITUTED PYRROLE MOIETIES - NEW SENSITIVE LAYER FOR IONIC ELECTROCHEMICAL DETECTION, Journal de chimie physique et de physico-chimie biologique, 95(6), 1998, pp. 1547-1550
Citations number
8
Categorie Soggetti
Biology,"Chemistry Physical
Journal title
Journal de chimie physique et de physico-chimie biologique → ACNP
Volume
95
Issue
6
Year of publication
1998
Pages
1547 - 1550
Database
ISI
SICI code
Abstract
A calix[4]arene modified by grafting N-substituted pyrrole moieties at the upper rim was synthetised. Electropolymerisation of this new cali x[4]arene in a Bu4NClO4 (10(-1) M) - CH3CN solution is described. The obtained film presents a rather stable electroactivity to electrochemi cal cycling but its growing is limited to a few monolayers. It's the f irst example of homopolymerisation of a calix[4]arene modified by elec tropolymerisable monomers.